What changes when you model the path
Rows are current states, and columns are next states. Starting calm gives tomorrow's state probabilities . The probability of being stressed in two days is the sum over the two possible intermediate states.
The probability of having seen stress at least once by day two is . A path that is stressed tomorrow and calm the following day counts toward the second probability because it passed through stress.
Here is the difference in path terms. Starting calm, the alert fires either when day one is stressed, with probability , or when day one stays calm and day two turns stressed, with probability . The second term excludes paths already counted on day one. To finish in stress, the path that starts by turning stressed must also stay stressed on day two, so that term becomes . The two questions use the same transition matrix and count different events.
Imagine a risk team whose monitoring process triggers an alert on the first stressed day in a two-day horizon. With the illustrative transition probabilities above, 19% is the probability of triggering the alert, while 15% is the probability of ending the horizon in stress. A terminal-state estimate would miss paths that triggered the alert and recovered.
A continuously monitored option barrier raises the same distinction with a price process. To estimate the knockout probability, the model has to describe whether paths reach the barrier during the life of the option. When using simulation, a coarse time grid can miss crossings between observation times.